Electrodeposition of hierarchically structured superhydrophobic Ni-PTFE composite coating with remarkable corrosion resistance, chemical and mechanical stability

Document Type : Article

Authors

Department of Materials Engineering, Science and Research Branch, Islamic Azad University, Tehran, Iran.

Abstract

One of the main problems of superhydrophobic coatings is the low mechanical and chemical stability, which limits the industrial applications of these coatings. The purpose of this research is to create Ni-PTFE composite coatings with hierarchical morphology by electrodeposition method, in order to increase the corrosion resistance, and to improve the mechanical and chemical stability. Ni-PTFE Composite coatings were fabricated by adding different concentrations of PTFE particles (5, 10, 15, 20, 30, and 40 g/L) into the Ni electrodeposition bath. The effect of PTFE concentration on morphology, wettability, and corrosion resistance of the coatings was investigated. The results showed that when an optimum concentration of PTFE (15 g/L) is introduced in the electrodeposition bath, not only the hierarchical morphology of the Ni coating is preserved; but also the maximum contact angle of 158° and the minimum corrosion current density of 0.03 µA/cm2 was achieved. The long-term chemical and mechanical stability tests showed that by embedding of PTFE particles with hydrophobic nature, into the hierarcically structured superhydrophobic nickel coatings, higher mechanical and chemical stability is obtaind.

Keywords

Main Subjects


References:
1. Ma, M. and Hill, R.M. "Superhydrophobic surfaces", Curr. Opin. Colloid Interface Sci., 11, pp. 193-202 (2006). https://doi.org/10.1016/j.cocis.2006.06.002.
2. Zhang, X., Shi, F., Niu, J., et al. "Superhydrophobic surfaces: from structural control to functional application", J. Mater. Chem., 18, pp. 621-633 (2008). DOI https://doi.org/10.1039/B711226B.
3. Guo, Z., Liu, W., and Su, B.L. "Superhydrophobic surfaces: from natural to biomimetic to functional", J. Colloid Interface Sci., 353, pp. 335-355 (2011). https://doi.org/10.1016/j.jcis.2010.08.047.
4. Darband, G.B., Aliofkhazraei, M., Khorsand, S., et al. "A science and engineering of superhydrophobic surfaces: review of corrosion resistance chemical and mechanical stability", Arabian J. Chem., 13, pp. 1763- 1802 (2020). https://doi.org/10.1016/j.arabjc.2018.01.013.
5. Khan, M.Z., Militky, J., Petru, M., et al. "Recent advances in superhydrophobic surfaces for practical applications: A review", Europ. Polym. J., 8, 111481 (2022). https://doi.org/10.1016/j.eurpolymj.2022.111481.
6. Li, W., Zhan, Y., Amirfazli, A., et al. "Recent progress in stimulus-responsive superhydrophobic surfaces", Prog. Org. Coat., 168, p. 106877 (2022). https://doi.org/10.1016/j.porgcoat.2022.106877.
7. Sam, E.K., Sam, D.K., Lv, X., et al. "Recent development in the fabrication of self-healing superhydrophobic surfaces", Chem. Eng. J., 373, pp. 531-546 (2019). https://doi.org/10.1016/j.cej.2019.05.077.
8. Sharma, D.K., Baghel, V., Kumar, R., et al. "Recent developments in fabrication of super-hydrophobic surfaces: A review", Adv. Ind. Prod. Eng., pp. 127-140 (2019). https://doi.org/10.1007/978-981-13-6412-9 12.
9. Wang, X., Ding, B., Yu, J., et al. "Engineering biomimetic superhydrophobic surfaces of electrospun nanomaterials", Nano Today, 6, pp. 510-530 (2011). https://doi.org/10.1016/j.nantod.2011.08.004.
10. Manca, M., Cannavale, A., De Marco, L., et al. "Durable superhydrophobic and antire ective surfaces by trimethylsilanized silica nanoparticles based sol- gel processing", Langmuir, 25, pp. 6357-6362 (2009). https://doi.org/10.1021/la804166t.
11. Ge-Zhang, S., Yang H., Ni, H., et al. "Biomimetic superhydrophobic metal/nonmetal surface manufactured by etching methods: A mini review", Front. Bioeng. Biotech., 10, p. 958095 (2022). https://doi.org/10.3389/fbioe.2022.958095.
12. Haghdoost, A. and Pitchumani, R. "Fabricating superhydrophobic surfaces via a two-step electrodeposition technique", Langmuir, 30, pp. 4183-4191 (2013). https://doi.org/10.1021/la403509d.
13. Xiang, T., Ding, S., Li, C., et al. "Effect of current density on wettability and corrosion resistance of superhydrophobic nickel coating deposited on low carbon steel", Mater. Des., 114, pp. 65-72 (2017). https://doi.org/10.1016/j.matdes.2016.10.047.
14. Olugbade, T.O., Abioye, T.E., Farayibi, P.K., et al. "Electrochemical properties of MgZnCa-based thin film metallic glasses fabricated by magnetron sputtering deposition coated on a stainless steel substrate", Anal. Lett., 54(10), pp. 1588-1602 (2021). https://doi.org/10.1080/00032719.2020.1815757.
15. Olugbade, T. and Lu, J. "Characterization of the corrosion of nanostructured 17-4 PH stainless steel by Surface Mechanical Attrition Treatment (SMAT)", Anal. Lett., 52(16), pp. 2454-2471 (2019). https://doi.org/10.1080/00032719.2019.1611842.
16. Olugbade, T., Liu, C., and Lu, J. "Enhanced passivation layer by Cr diffusion of 301 stainless steel facilitated by SMAT", Adv. Eng. Mater., 21, 1900125 (2019). https://doi.org/10.1002/adem.201900125.
17. Olugbade, T. and Lu, J. "Enhanced corrosion properties of nanostructured 316 stainless steel in 0.6 M NaCl solution", J. Bio. Tribo. Corros., 5, p. 38 (2019). https://doi.org/10.1007/s40735-019-0235-7.
18. Olugbade, T. "Electrochemical characterization of the corrosion of mild steel in saline following mechanical deformation", Anal. Lett., 54, pp. 1055-1067 (2021). https://doi.org/10.1080/00032719.2020.1793994.
19. Chen, Z., Tian, F., Hu, A., et al. "A facile process for preparing superhydrophobic nickel films with stearic acid", Surf. Coat. Technol., 231, pp. 88-92 (2013). https://doi.org/10.1016/j.surfcoat.2012.01.053.
20. Hashemzadeh, M., Raeissi, K., Ashrafizadeh, F., et al. "Effect of ammonium chloride on microstructure, super-hydrophobicity and corrosion resistance of nickel coatings", Surf. Coat. Technol., 283, pp. 318-328 (2015). https://doi.org/10.1016/j.surfcoat.2015.11.008.
21. Rahimi, E., Rafsanjani-Abbasi, A., Kiani-Rashid, A., et al. "Morphology modification of electrodeposited superhydrophobic nickel coating for enhanced corrosion performance studied by AFM, SEM-EDS and electrochemical measurements", Colloids Surf. A., 547, pp. 81-94 (2018). https://doi.org/10.1016/j.colsurfa.2018.03.045.
22. Su, F., Yao, K., Liu, C., et al. "Rapid fabrication of corrosion resistant and superhydrophobic cobalt coating by a one-step electrodeposition", J. Electrochem. Soc., 160, pp. D593-D599 (2013). DOI: 10.1149/2.047311jes.
23. She, Z., Li, Q., Wang, Z., et al. "Novel method for controllable fabrication of a superhydrophobic CuO surface on AZ91D magnesium alloy", ACS Appl. Mater. Interfaces, 4, pp. 4348-4356 (2012). https://doi.org/10.1021/am3009949.
24. Niu, S., Fang, Y., Qiu, R., et al. "Superhydrophobic film based on Cu-dodecanethiol complex: preparation and corrosion inhibition for Cu", Colloids Surf. A., 550, pp. 65-73 (2018). https://doi.org/10.1016/j.colsurfa.2018.04.023.
25. Khorsand, S., Raeissi, K., Ashrafizadeh, F., et al. "Corrosion behaviour of super-hydrophobic electrodeposited nickel-cobalt alloy film", Appl. Surf. Sci., 364, pp. 349-357 (2016). https://doi.org/10.1016/j.apsusc.2015.12.122.
26. Su, F. and Yao, K. "Facile fabrication of superhydrophobic surface with excellent mechanical abrasion and corrosion resistance on copper substrate by a novel method", ACS Appl. Mater. Interfaces, 6, pp. 8762- 8770 (2014). https://doi.org/10.1021/am501539b.
27. Yu, Q., Zeng, Z., Zhao, W., et al. "Patterned Ni-P alloy films prepared by "Reducing-discharging" process and the hydrophobic rpoperty", ACS Appl. Mater. Interfaces, 6, pp. 1053-1060 (2014). https://doi.org/10.1021/am404590d.
28. Hang, T., Hu, A., Ling, H., et al. "Super-hydrophobic nickel films with micro-nano hierarchical structure prepared by electrodeposition", Appl. Surf. Sci., 256, pp. 2400-2404 (2010). https://doi.org/10.1016/j.apsusc.2009.10.074.
29. Barati Darband, G., Aliofkhazraei, M., and Sabour Rouhaghdam, A. "Nickel nanocones as efficient and stable catalyst for electrochemical hydrogen evolution reaction", Int. J. Hydrogen Energy, 42, pp. 14560- 14565 (2017). https://doi.org/10.1016/j.ijhydene.2017.04.120.
30. Ran, M., Zheng, W., and Wang, H. "Fabrication of superhydrophobic surfaces for corrosion protection: a review", Mater. Sci. Technol., 35, pp. 313-326 (2019). https://doi.org/10.1080/02670836.2018.1560985.
31. Wang, Y., Wang, W., Zhong, L., et al. "Superhydrophobic surface on pure magnesium substrate by wet chemical method", Appl. Surf. Sci., 256, pp. 3837- 3840 (2010). https://doi.org/10.1016/j.apsusc.2010.01.037.
32. Zhang, J., Li, J., and Han, Y. "Superhydrophobic PTFE surfaces by extension", Macromol. Rapid Commun., 25, pp. 1105-1108 (2004).https://doi.org/10.1002/marc.200400065.
33. Iacovetta, D., Tam, J., and Erb, U "Synthesis, structure, and properties of superhydrophobic nickel-PTFE nanocomposite coatings made by electrodeposition", Surf. Coat. Technol., 279, pp. 134-141 (2015). https://doi.org/10.1016/j.surfcoat.2015.08.022.
34. Chen, Z., Li, F., Hao, L., et al. "One-step  lectrodeposition process to fabricate cathodic superhydrophobic surface", Appl. Surf. Sci., 258, pp. 1395-1398 (2011). https://doi.org/10.1016/j.apsusc.2011.09.086.
35. Piwowarczyk, J., Jedrzejewski, R., Moszynski, D., et al. "XPS and FT IR studies of polytetra uoroethylene thin films obtained by physical methods", Polymers, 11, pp. 1629-1641 (2019). https://doi.org/10.3390/polym11101629.
36. Wang, H., Di, D., Zhao, Y., et al. "A multifunctional polymer composite coating assisted with pore-forming agent: Preparation, superhydrophobicity and corrosion resistance", Prog. Org. Coat., 132, pp. 370-378 (2019). https://doi.org/10.1016/j.porgcoat.2019.04.027.
37. Khorsand, S., Raeissi, K., and Ashrafizadeh, F. "Corrosion resistance and long-term durability of superhydrophobic nickel film prepared by electrodeposition process", Appl. Surf. Sci., 305, pp. 498-505 (2014). https://doi.org/10.1016/j.apsusc.2014.03.123.
38. Orazem, M.E. and Tribollet, B., Electrochemical Impedance Spectroscopy, Wiley-Interscience: Hoboken, NJ (2008).
39. Tam, J., Jiao, Z., Lau, J.C.F., et al. "Wear stability of superhydrophobic nano Ni-PTFE electrodeposits", Wear, 374, pp. 1-4 (2017). https://doi.org/10.1016/j.wear.2016.12.023.
40. Guo, Z., Zhou, F., Hao, J., et al "Stable biomimetic super-hydrophobic engineering materials", J. Am. Chem. Soc., 127, pp. 15670-15671 (2005). https://doi.org/10.1021/ja0547836.