The heterobinuclear platinum(0)-gold(I) complex [(t-Bu3P)2PtAu(PPh3)] BF4, 5, was synthesized by the reaction of trinuclear cluster complex f[(PPh3)Au]3(- O)gBF4, 4, with one equiv of [(t-Bu3P)2Pt] at room temperature. The heterobinuclear complex 5 was characterized using multinuclear NMR spectroscopy and elemental microanalysis and was further identi ed by single crystal X-ray structure determination. Crystal structure of 5 shows a T-shaped geometry with an unsupported short distance Pt-Au dative bond.
Jamali, S., Ashtiani, M., & Milic, D. (2016). Synthesis of a new T-shaped heterobinuclear Pt0-AuI complex [(t-Bu3P)2PtAu(PPh3)]BF4 from trinuclear gold cluster complex [(PPh3)Au]3(-O)BF4. Scientia Iranica, 23(3), 1089-1094. doi: 10.24200/sci.2016.3878
MLA
S. Jamali; M.M. Ashtiani; D. Milic. "Synthesis of a new T-shaped heterobinuclear Pt0-AuI complex [(t-Bu3P)2PtAu(PPh3)]BF4 from trinuclear gold cluster complex [(PPh3)Au]3(-O)BF4". Scientia Iranica, 23, 3, 2016, 1089-1094. doi: 10.24200/sci.2016.3878
HARVARD
Jamali, S., Ashtiani, M., Milic, D. (2016). 'Synthesis of a new T-shaped heterobinuclear Pt0-AuI complex [(t-Bu3P)2PtAu(PPh3)]BF4 from trinuclear gold cluster complex [(PPh3)Au]3(-O)BF4', Scientia Iranica, 23(3), pp. 1089-1094. doi: 10.24200/sci.2016.3878
VANCOUVER
Jamali, S., Ashtiani, M., Milic, D. Synthesis of a new T-shaped heterobinuclear Pt0-AuI complex [(t-Bu3P)2PtAu(PPh3)]BF4 from trinuclear gold cluster complex [(PPh3)Au]3(-O)BF4. Scientia Iranica, 2016; 23(3): 1089-1094. doi: 10.24200/sci.2016.3878
)