Chemistry and Chemical Engineering Research Center of Iran P.O.Box 14335-186, Tehran, Iran
Abstract
A room-temperature procedure is developed for the direct synthesis of monoarylidene derivatives of pyran-4-one and piperidin-4-one systems under solvent-free conditions. Relatively high yields of products are obtained from the reaction of ketones 1 with different aromatic and aliphatic aldehydes under the catalytic system of TMSNMe2 and MgBr2·OEt2. Notably, formation of the undesired bis counterparts as a major limitation of these reaction types, is minimized using the employed conditions.
Mojtahedi,M M , Abaee,M S , Samianifard,M and Shamloo,A . (2014). An efficient synthesis of monoarylidene derivatives of pyran-4-one and piperidin-4-one. Scientia Iranica, 21(3), 719-726.
MLA
Mojtahedi,M M , , Abaee,M S , , Samianifard,M , and Shamloo,A . "An efficient synthesis of monoarylidene derivatives of pyran-4-one and piperidin-4-one", Scientia Iranica, 21, 3, 2014, 719-726.
HARVARD
Mojtahedi M M, Abaee M S, Samianifard M, Shamloo A. (2014). 'An efficient synthesis of monoarylidene derivatives of pyran-4-one and piperidin-4-one', Scientia Iranica, 21(3), pp. 719-726.
CHICAGO
M M Mojtahedi, M S Abaee, M Samianifard and A Shamloo, "An efficient synthesis of monoarylidene derivatives of pyran-4-one and piperidin-4-one," Scientia Iranica, 21 3 (2014): 719-726,
VANCOUVER
Mojtahedi M M, Abaee M S, Samianifard M, Shamloo A. An efficient synthesis of monoarylidene derivatives of pyran-4-one and piperidin-4-one. Scientia Iranica. 2014;21(3):719-726.
