Chemistry Department, Faculty of Sciences, Persian Gulf University, Bushehr, 75169, Iran
Abstract
A simple and efficient procedure for the preparation of 3-propyldiethylenetriaminesilica (PDTAS) by reaction of 3-chloropropylsilica with diethylene-triamine is described. 3-Propyldiethylenetriaminesilicais employed as a recyclable base catalyst for the synthesis of 2-amino-4,6-diarylnicotininitrilefrom the reaction of acetophenone derivatives, aromatic aldehydes, malononitrile, and ammonium acetate under solvent-free conditions at 100 oC. The heterogeneous solid base catalyst was recycled for four runs upon the reaction of 4-chloroacetophenone, 4-chloroenzaldehyde, malononitrile, and ammonium acetate without losing its catalytic activity.
Niknam, K. , Rashidian, R. and Jamali, A. (2013). Synthesis of 2-amino-4,6-diarylnicotininitriles using 3-propyldiethylenetriamine-silica as a recyclable solid base catalyst. Scientia Iranica, 20(6), 1863-1870.
MLA
Niknam, K. , , Rashidian, R. , and Jamali, A. . "Synthesis of 2-amino-4,6-diarylnicotininitriles using 3-propyldiethylenetriamine-silica as a recyclable solid base catalyst", Scientia Iranica, 20, 6, 2013, 1863-1870.
HARVARD
Niknam, K., Rashidian, R., Jamali, A. (2013). 'Synthesis of 2-amino-4,6-diarylnicotininitriles using 3-propyldiethylenetriamine-silica as a recyclable solid base catalyst', Scientia Iranica, 20(6), pp. 1863-1870.
CHICAGO
K. Niknam , R. Rashidian and A. Jamali, "Synthesis of 2-amino-4,6-diarylnicotininitriles using 3-propyldiethylenetriamine-silica as a recyclable solid base catalyst," Scientia Iranica, 20 6 (2013): 1863-1870,
VANCOUVER
Niknam, K., Rashidian, R., Jamali, A. Synthesis of 2-amino-4,6-diarylnicotininitriles using 3-propyldiethylenetriamine-silica as a recyclable solid base catalyst. Scientia Iranica, 2013; 20(6): 1863-1870.
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