Atmospheric Emissions of Volatile Organic Compounds From a Solvent Paint Sludge - Chemical Identification and Quantification

Document Type : Research Article

Authors

1 aLaboratory of Soft Technologies, Physicochemical, Valorization of Biological Materials and Biodiversity, Chemistry Department, Faculty of Sciences, M’hamed Bougara University, Boumerdes 35000 (Algeria)

2 - Laboratory of Soft Technologies, Physicochemical, Valorization of Biological Materials and Biodiversity, Chemistry Department, Faculty of Sciences, M’hamed Bougara University, Boumerdes 35000 (Algeria) - Laboratory of Applied Chemistry and Materials, Chemistry Department, Faculty of Sciences, M’hamed Bougara University, Boumerdes 35000 (Algeria)

3 Department of Chemical Engineering, BiotecnIA Group, University of Vigo, Vigo36310, (Spain)

10.24200/sci.2025.65747.9643

Abstract

Solvent based paint sludge contains volatile organic compounds (VOCs) that negatively impact both ecosystems and human health. These VOCs contribute to ground-level ozone formation and are key precursors in the creation of secondary organic pollutants in the atmosphere. There are limited studies that quantify the gaseous compounds released from solvent based paint sludge. In this context, we conducted our experimental study on detection of gaseous emission from paint sludge samples taken from an Algerian paint industry, in both short and long period of storage. Results revealed that paint sludge samples emitted a wide range of VOCs; over 36 compounds were identified, quantified and classified into different chemical groups. Among the compounds identified, aliphatic hydrocarbons, aromatic hydrocarbons, esters, ketones and alkanes. The collected sample from the waste storage area(PS2)contains a higher concentration of oxygenated compounds than those collected in the regeneration station (PS1) and in the waste storage chamber (PS3). Therefore, the gas emitted from paint sludge increased depending on the type and duration of storage. Given that many of the identified VOCs are carcinogenic, toxic, or harmful by inhalation, it is essential to regulate gas emissions during waste management and treatment.

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Articles in Press, Accepted Manuscript
Available Online from 11 May 2025
  • Receive Date: 30 November 2024
  • Revise Date: 25 March 2025
  • Accept Date: 20 April 2025