Chemistry and Chemical Engineering Research Center of Iran P.O.Box 14335-186, Tehran, Iran
Abstract
A room-temperature procedure is developed for the direct synthesis of monoarylidene derivatives of pyran-4-one and piperidin-4-one systems under solvent-free conditions. Relatively high yields of products are obtained from the reaction of ketones 1 with different aromatic and aliphatic aldehydes under the catalytic system of TMSNMe2 and MgBr2·OEt2. Notably, formation of the undesired bis counterparts as a major limitation of these reaction types, is minimized using the employed conditions.
Mojtahedi, M. M., Abaee, M. S., Samianifard, M., & Shamloo, A. (2014). An efficient synthesis of monoarylidene derivatives of pyran-4-one and piperidin-4-one. Scientia Iranica, 21(3), 719-726.
MLA
Mohammad M. Mojtahedi; M. Saeed Abaee; Maedeh Samianifard; Akram Shamloo. "An efficient synthesis of monoarylidene derivatives of pyran-4-one and piperidin-4-one". Scientia Iranica, 21, 3, 2014, 719-726.
HARVARD
Mojtahedi, M. M., Abaee, M. S., Samianifard, M., Shamloo, A. (2014). 'An efficient synthesis of monoarylidene derivatives of pyran-4-one and piperidin-4-one', Scientia Iranica, 21(3), pp. 719-726.
VANCOUVER
Mojtahedi, M. M., Abaee, M. S., Samianifard, M., Shamloo, A. An efficient synthesis of monoarylidene derivatives of pyran-4-one and piperidin-4-one. Scientia Iranica, 2014; 21(3): 719-726.
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